Search results for "P-chirogenic phosphine ligand"

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Phospholylmethano P-chirogenic-phosphine-borane as P-(η2-BH3)-chelating ligands of rhodium (I): Synthesis, characterization and asymmetric hydrogenat…

2021

International audience; The stereoselective synthesis of new phospholylmethano P-chirogenic-phosphine-borane was achieved by P-C bond formation of the bridge, using electrophilic or nucleophilic P*-building blocks. These P1CH2P2*.BH3 ligands behaved as chelating (κ1-P1)-(η2-BH3) entities towards the cationic rhodium(I) centre. The resulting chiral rhodium complexes were tested in asymmetric rhodium catalyzed hydrogenation of methyl 2-(acetamido)acrylate.

chemistry.chemical_elementBorane010402 general chemistry01 natural sciencesBiochemistryMedicinal chemistryRhodiumCatalysisInorganic Chemistrychemistry.chemical_compoundNucleophileMaterials Chemistry[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical Chemistry010405 organic chemistryOrganic ChemistryAsymmetric hydrogenationCationic polymerizationStereoselective synthesis0104 chemical sciences3. Good healthP-chirogenic phosphine ligandCoordination chemistrychemistryAsymmetric hydrogenationElectrophilePhosphine

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